Nate/Blair/Chuck
Credit:Giovanni Rufino/The CW
As it is written in the Bro Code: one bro cannot scam on another bro's girl. But codes don't really apply to Chuck Bass, so it's no surprise he jumped in the sack (er, limo) with best friend Nate's girlfriend Blair early on in season one of "Gossip Girl." Things were tense for a bit, but Nate warmed up to his friends after a fling with a middle-aged duchess.
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